| dc.contributor.author | Karabulut, Solmaz | |
| dc.contributor.author | Sariaslan, Begum | |
| dc.contributor.author | Ozturk, Bengi Ozgun | |
| dc.date.accessioned | 2019-12-17T07:07:47Z | |
| dc.date.available | 2019-12-17T07:07:47Z | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 1566-7367 | |
| dc.identifier.uri | https://doi.org/10.1016/j.catcom.2013.06.023 | |
| dc.identifier.uri | http://hdl.handle.net/11655/20455 | |
| dc.description.abstract | In this study, we report a practical catalytic system, [RuCl2( p-cymene)](2)/IPr (IPr: 1,3-bis(2,6 diisopropylphenyl) imidazol-2-ylidene), that can switch between cyclotrimerization and cross enyne metathesis. The cyclotrimerization reaction of phenylacetylene catalyzed by [RuCl2(p-cymene)](2) can be switched to enyne metathesis by the introduction of a sterically hindered N-heterocyclic carbene. The 1,3-diene formed during this reaction reacts with dienophiles to form the Diels-Alder adduct. A practical one-pot synthesis method, utilizing enyne metathesis/Diels-Alder reactions, was used to construct cyclic compounds in an efficient manner. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.relation.isversionof | 10.1016/j.catcom.2013.06.023 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | Chemistry | |
| dc.title | A Ruthenium-Based Catalytic System with Switchable Selectivity Between Cyclotrimerization and Enyne Metathesis/Diels-Alder Reactions of Terminal Alkynes | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
| dc.relation.journal | Catalysis Communications | |
| dc.contributor.department | Matematik ve Fen Bilimleri Eğitimi | |
| dc.identifier.volume | 41 | |
| dc.identifier.startpage | 12 | |
| dc.identifier.endpage | 16 | |
| dc.description.index | WoS | |
| dc.description.index | Scopus | |
