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A Ruthenium-Based Catalytic System with Switchable Selectivity Between Cyclotrimerization and Enyne Metathesis/Diels-Alder Reactions of Terminal Alkynes

Karabulut, Solmaz; Sariaslan, Begum; Ozturk, Bengi Ozgun (Elsevier, 2013)

In this study, we report a practical catalytic system, [RuCl2( p-cymene)](2)/IPr (IPr: 1,3-bis(2,6 diisopropylphenyl) imidazol-2-ylidene), that can switch between cyclotrimerization and cross enyne metathesis. The ...