Show simple item record

An Anomalous Addition Of Chlorosulfonyl Isocyanate To A Carbonyl Group: The Synthesis Of ((3As,7Ar,E)-2-Ethyl-3-Oxo-2,3,3A,4,7,7A-Hexahydro-1H-Isoindol-1-Ylidene)Sulfamoyl Chloride

dc.contributor.authorKöse, Aytekin
dc.contributor.authorÜnal, Aslı
dc.contributor.authorŞahin, Ertan
dc.contributor.authorBozkaya, Uğur
dc.contributor.authorKara, Yunus
dc.date.accessioned2021-06-09T06:47:11Z
dc.date.available2021-06-09T06:47:11Z
dc.date.issued2019
dc.identifier.issn1860-5397
dc.identifier.urihttp://dx.doi.org/10.3762/bjoc.15.89
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541324/
dc.identifier.urihttp://hdl.handle.net/11655/24865
dc.description.abstractIn this study, we developed a new addition reaction of chlorosulfonyl isocyanate (CSI), starting from 2-ethyl-3a,4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione. The addition reaction of CSI with 2-ethyl-3a,4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione resulted in the formation of ylidenesulfamoyl chloride, whose exact configuration was determined by X-ray crystal analysis. We explain the mechanism of product formation supported by theoretical calculations.
dc.language.isoen
dc.relation.isversionof10.3762/bjoc.15.89
dc.rightsAttribution 4.0 United States
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.titleAn Anomalous Addition Of Chlorosulfonyl Isocyanate To A Carbonyl Group: The Synthesis Of ((3As,7Ar,E)-2-Ethyl-3-Oxo-2,3,3A,4,7,7A-Hexahydro-1H-Isoindol-1-Ylidene)Sulfamoyl Chloride
dc.title.alternativeAn anomalous addition of chlorosulfonyl isocyanate to a carbonyl group
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalBeilstein Journal Of Organic Chemistry
dc.contributor.departmentKimya
dc.identifier.volume15
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


Files in this item

Name:
scd33.pdf
Size:
1.888Mb
Format:
PDF
View/Open

This item appears in the following Collection(s)

Show simple item record

Attribution 4.0 United States
Except where otherwise noted, this item's license is described as Attribution 4.0 United States