Poly[(Μ5-2,2′-Bipyridine-5,5′-DicarboxylAto)Lead(Ii)]
Date
2012Author
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Çevik, Sabri
Necefoğlu, Hacali
Hökelek, Tuncer
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In the title polymeric compound, [Pb(C12H6N2O4)]n, the PbII cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′-dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.
URI
https://doi.org/10.1107/S1600536812035647https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435613/
http://hdl.handle.net/11655/18445