1-{2-(4-ChloroBenzYloxy)-2-[4-(MorPhoLin-4-Yl)PhenYl]EthYl}-1H-Benzimidazole Propan-2-Ol Monosolvate
Date
2013Author
Güven, Özden Özel
Çapanlar, Seval
Adler, Philip D. F.
Coles, Simon J.
Hökelek, Tuncer
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In the title compound, C26H26ClN3O2·C3H7OH, the benzimidazole ring system is essentially planar [maximum deviation = −0.018 (2) Å] and its mean plane is oriented with respect to the two benzene rings at dihedral angles of 4.51 (6) and 56.16 (6)°, and the dihedral angle between the two benzene rings is 59.11 (7)°. The morpholine ring displays a chair conformation. The propan-2-ol solvent molecule links with the benzimidazole ring via an O—H⋯N hydrogen bond. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link the molecules into inversion dimers with an R 2 2(28) motif. π–π stacking occurs between the parallel chlorobenzene rings [centroid–centroid distance = 3.792 (1) Å]. Weak C—H⋯π interactions and short Cl⋯Cl [3.2037 (10) Å] contacts are also observed.
URI
https://doi.org/10.1107/S1600536813022599https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884486/
http://hdl.handle.net/11655/18053