DiaquaBis(N,N-DiethylNicotinamide-Κn1)Bis(4-FormylBenzoato-Κo)Cobalt(Ii)
Date
2009Author
Sertçelik, Mustafa
Necefoğlu, Hacali
Tercan, Barış
Şahin, Ertan
Hökelek, Tuncer
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In the crystal structure of the title CoII complex, [Co(C8H5O3)2(C10H14N2O)2(H2O)2], the metal centre is located on an inversion center and is coordinated by two 4-formylbenzoate (FOB), two diethylnicotinamide (DENA) ligands and two water molecules in a slightly distorted CoO4N2 octahedral geometry. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into infinite chains. π–π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid–centroid distance = 3.652 (3) Å] further stabilize the crystal structure.
URI
https://doi.org/10.1107/S1600536809008265https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968947/
http://hdl.handle.net/11655/18300