AquaBis(4-FluoroBenzoato-Κo)bis(Nicotinamide-Κn 1)Copper(II) Nicotinamide Hemisolvate Trihydrate
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Date
2012Author
Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, V.
Adigüzel, V.
Hökelek, Tuncer
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The asymmetric unit of the title compound, [Cu(C7H4FO2)2(C6H6N2O)2(H2O)]·0.5C6H6N2O·3H2O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The CuII ion is coordinated by two O atoms from two 4-fluorobenzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds consolidate the crystal packing, which also exhibits π–π interactions between the aromatic rings [centroid–centroid distances 3.692 (2)–3.794 (2) Å].
URI
https://doi.org/10.1107/S1600536811053116https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254320/
http://hdl.handle.net/11655/18113