Özet
One of the most important steps in establishing a biogas plant is the realistic modeling of the biogas plants. With the modeling operation, suitable operating conditions can be selected for the biogas plants. From this point of view, in this study, the Anaerobic Treatment Model No 1 (ADM1) giving results which have low error rates used in the modeling of treatment plants model was applied and a biogas plants using chicken manure and two cattle waste with different organic contents were modeled.
The ADM1 model consists of a series of dynamic and steady-state processes and over 200 input parameters. In the model, the activities of microorganisms which are effective in the treatment process in the anaerobic reactor are defined by mathematical expressions obtained from experimental results. In order to be able to analyze by using different waste types at different temperatures and organic loading rates, various changes have to be made on the model. The necessary arrangements in this study were made using the results found in the literature studies.
The model study was carried out for organic loading rates (OLR) of 1, 1.5 and 2 kg VS / d m3 respectively at temperatures of 35 °C, 30 °C and 25 °C chicken waste and for cattle manure having high organic content. Modeling for bovine waste with low organic content was carried out at 35 °C for OLR of 2 kg VS / d m3. In order to compare cattle waste with low and high organic content, the modeling work was carried out at a temperature of 35 °C and an organic loading rate of 2 kg VS / d m3. In this study, the amount of biogas production, the content of biogas methane, the biogas and methane production per gram of volatile solid material and the pH value in the reactor were investigated. Under the different modeling conditions, outputs are compared and the most advantageous situations are expressed.
As a result of the modeling study, it was observed that the biogas production and the biogas and methane production per gram of volatile solid material (VS) pH level were increased when the operating temperature was increased. Whereas methane content of the biogas was has not changed significantly. It has been observed that when the organic loading rate is increased, the biogas and methane production per gram of volatile solid material and pH level decreases. Higher organic content of chicken waste resulted in higher biogas production, the biogas and methane production per gram of VS under all conditions compared to cattle waste with high organic content. As expected, higher biogas and biogas, methane production per gram of VS were obtained in each case from cattle manure having high organic content than in cattle manure having low organic content.
As a result of the analysis made with ADM1, it was observed that the model gave appropriate results to the experimental studies in the literature.
Künye
[1] Anonim, “Enerji Atlası,” http://www.enerjiatlasi.com/biyogaz/, http://www.enerjiatlasi.com/biyogaz/ (Mayıs 2017).
[2] P. Lusk, “Methane Recovery from Animal Manures The Current Opportunities Casebook,” Midwest Res. Inst. U.S. Dep. Energy, no. September, p. 150, 1998.
[3] W. Asvapoositkul, J. Joraden, and S. Wongwises, “Asian Journal on Energy and Environment,” vol. 6, no. 3, pp. 154–164, 2005.
[4] N. J. Themelis, “NAWTEC12-2231 Combining Anaerobic Digestion and Waste-To-Energy,” pp. 265–271, 2004.
[5] M. and D. C. Davis, Introduction to Environmental Engineering. New York: WCB/McGraw-Hill, 1998.
[6] T. Conant, A. Karim, and A. Datye, “Coating of steam reforming catalysts in non-porous multi-channeled microreactors,” Bioresour. Technol., vol. 99, no. 4, pp. 882–888, 2008.
[7] L. Jiunn-Jyi, L. Yu-You, and T. Noike, “Influences of pH and moisture content on the methane production in high-solids sludge digestion,” Water Res., vol. 31, no. 6, pp. 1518–1524, 1997.
[8] R. Y. Morita, “Psychrophilic Bacteria1,” vol. 39, no. 2, pp. 144–167, 1975.
[9] K. J. Chae, A. Jang, S. K. Yim, and I. S. Kim, “The effects of digestion temperature and temperature shock on the biogas yields from the mesophilic anaerobic digestion of swine manure,” Bioresour. Technol., vol. 99, no. 1, pp. 1–6, 2008.
[10] Y. Miron, G. Zeeman, J. B. Van Lier, and G. Lettinga, “The role of sludge retention time in the hydrolysis and acidification of lipids, carbohydrates and proteins during digestion of primary sludge in CSTR systems,” Water Res., vol. 34, no. 5, pp. 1705–1713, 2000.
[11] A. Babaee and J. Shayegan, “Effect of Organic Loading Rates (OLR) on Production of Methane from Anaerobic Digestion of Vegetables Waste,” World Renew. energy Congr., pp. 411–417, 2011.
[12] M. Henze et al., “Activated Sludge Model No.2d, ASM2d,” Water Sci. Technol., vol. 39, no. 1, pp. 165–182, 1999.
[13] W. Gujer, M. Henze, T. Mino, and M. Van Loosdrecht, “Activated Sludge Model No. 3,” Water Sci. Technol., vol. 39, no. 1, pp. 183–193, 1999.
[14] D. J. Batstone et al., “The IWA Anaerobic Digestion Model No 1 (ADM1).,” Water Sci. Technol., vol. 45, no. 10, pp. 65–73, 2002.
[15] R. L. . Gossett, James M.,Belser, “Anaerobic digestion of waste activated sludge,” J. Environ. Eng. Div., no. 108(EE6), pp. 1101–20, 1982.
[16] S. G. Pavlostathis and J. M. Gossett, “A kinetic model for anaerobic digestion of biological sludge,” Biotechnol. Bioeng., vol. 28, no. 10, pp. 1519–1530, 1986.
[17] C. Rosen, D. Vrecko, K. V Gernaey, and U. Jeppsson, “Implementing ADM1 for benchmark simulations in Matlab / Simulink,” Water Sci. Technol., vol. 54, no. 4, pp. 11–19, 2006.
[18] K. Koch, M. Lübken, T. Gehring, M. Wichern, and H. Horn, “Biogas from grass silage - Measurements and modeling with ADM1,” Bioresour. Technol., vol. 101, no. 21, pp. 8158–8165, 2010.
[19] M. Myint, N. Nirmalakhandan, and R. E. Speece, “Anaerobic fermentation of cattle manure: Modeling of hydrolysis and acidogenesis,” Water Res., vol. 41, no. 2, pp. 323–332, 2007.
[20] B. Wett, A. Eladawy, and M. Ogurek, “Description of nitrogen incorporation and release in ADM1,” IWA Publ., vol. 54, no. 4, pp. 67–76, 2006.
[21] X. Qu et al., “Anaerobic biodegradation of cellulosic material: Batch experiments and modelling based on isotopic data and focusing on aceticlastic and non-aceticlastic methanogenesis,” Waste Manag., vol. 29, no. 6, pp. 1828–1837, 2009.
[22] P. Satpathy, S. Steinigeweg, F. Uhlenhut, and E. Siefert, “Application of Anaerobic Digestion Model 1 (ADM1) for Prediction of Biogas Production,” Int. J. Sci. Eng. Res., vol. 4, no. 12, pp. 86–89, 2013.
[23] F. Blumensaat and J. Keller, “Modelling of two-stage anaerobic digestion using the IWA Anaerobic Digestion Model No. 1 (ADM1),” Water Res., vol. 39, no. 1, pp. 171–183, 2005.
[24] W. Stumm and J. J. Morgan, “Chemical Equilibria and Rates in Natural Waters,” Aquat. Chem., p. 1022, 1996.
[25] D. J. Batstone, “High rate anaerobic treatment of complex wastewater,” no. Clm, p. 200, 2000.
[26] D. J. Costello, Modelling, Optimisation, and Control of High-rate Anaerobic Reactors. University of Queensland, 1989.
[27] M. Romli, “Modelling and verification of a two-stage high-rate anaerobic wastewater treatment system,” University of Queensland, 1993.
[28] I. R. Ramsay, Modelling and Control of High-rate Anaerobic Wastewater Treatment Systems. University of Queensland, 1997.
[29] A. Galí, T. Benabdallah, S. Astals, and J. Mata-Alvarez, “Modified version of ADM1 model for agro-waste application,” Bioresour. Technol., vol. 100, no. 11, pp. 2783–2790, 2009.
[30] D. I. Page, K. L. Hickey, R. Narula, A. L. Main, and S. J. Grimberg, “Modeling anaerobic digestion of dairy manure using the IWA Anaerobic Digestion Model no. 1 (ADM1),” Water Sci. Technol., vol. 58, no. 3, pp. 689–695, 2008.
[31] C. Rosen and U. Jeppsson, “Aspects on ADM1 Implementation within the BSM2 Framework,” Tech. Rep., pp. 1–37, 2006.
[32] A. Normak, J. Suurpere, K. Orupõld, E. Jõgi, and E. Kokin, “Simulation of anaerobic digestion of cattle manure,” Agron. Res., vol. 10, no. SPEC. ISS. 1, pp. 167–174, 2012.
[33] D. Der Naturwissenschaften and H. P. Biernacki, “Model based sustainable production of biomethane,” 2014.
[34] W. H. Bergland, C. Dinamarca, and R. Bakke, “Temperature Effects in Anaerobic Digestion Modeling,” Proc. 56th SIMS, no. 1, pp. 261–269, 2015.
[35] Arikan, O. A., Mulbry, W., & Lansing, S., Effect of temperature on methane production from field-scale anaerobic digesters treating dairy manure. Waste Management, 43, 108-113, 2015.
[36] Babaee, Azadeh, and Jalal Shayegan. "Effect of organic loading rates (OLR) on production of methane from anaerobic digestion of vegetables waste." World Renewable Energy Congress-Sweden; 8-13 May; 2011; Linköping; Sweden. No. 57. Linköping University Electronic Press, 2011.
[37] Kestutis, N., Kestutis, V., Arnas, P. and Vidmantas, Z., INFLUENCE OF TEMPERATURE VARIATION ON BIOGAS YIELD FROM INDUSTRIAL WASTES AND ENERGY PLANTS. In: ENGINEERING FOR RURAL DEVELOPMENT, 2013.
[38] Dalkılıc, K., & Ugurlu, A., Biogas production from chicken manure at different organic loading rates in a mesophilic-thermopilic two stage anaerobic system. Journal of bioscience and bioengineering, 120(3), 315-322, 2015.
[39] Wang, F., Zhang, C., & Huo, S., Influence of fluid dynamics on anaerobic digestion of food waste for biogas production. Environmental technology, 38(9), 1160-1168, 2017.