dc.contributor.author | Zaman, İbrahim Göker | |
dc.contributor.author | Çaylak Delibas, Nagihan | |
dc.contributor.author | Necefoglu, Hacali | |
dc.contributor.author | Hökelek,Tuncer | |
dc.date.accessioned | 2019-12-13T06:27:00Z | |
dc.date.available | 2019-12-13T06:27:00Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536812004357 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297223/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18143 | |
dc.description.abstract | In the crystal of the title polymeric compound, {[Pb(C7H5O3)2(C6H6N2O)]·H2O}n, the PbII ion is chelated by two carboxylate groups of 3-hydroxybenzoate (HB) anions, and coordinated by one isonicotinamide molecule; a carboxylate O atom and a hydroxy O atom from adjacent HB anions bridge the PbII ion to form polymeric chains along [100], in which the PbII ion is in an irregular seven-coordination geometry. The carboxylate groups of the HB ions are slightly twisted away from the attached benzene rings by 2.84 (15) and 4.8 (2)°. The planes of the two benzene rings of the HB ions are oriented with respect to each other at a dihedral angle of 84.41 (8)°. In the crystal, adjacent polymeric chains interact via O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds. The solvent water molecule links with the polymeric chains via O—H⋯O hydrogen bonding. π–π stacking between the benzene and pyridine rings and between the benzene rings [centroid–centroid distances = 3.731 (2) and 3.353 (2) Å] are present in the crystal. | |
dc.relation.isversionof | 10.1107/S1600536812004357 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Catena-Poly[[(Μ-3-HyDroxyBenzoato-Κ3 O 1,O 1′:O 3)(Μ-3-HyDroxyBenzoato-Κ3 O 1,O 1′:O 1)(Isonicotinamide-Κn 1)Lead(Ii)] Monohydrate] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 68 | |
dc.identifier.issue | Pt 3 | |
dc.identifier.startpage | m257 | |
dc.identifier.endpage | m258 | |
dc.description.index | PubMed | |
dc.description.index | Scopus | |