Electro-Induced Early Transition Metal Metathesis Catalyst Systems For The Production Of Polyacetylene

dc.contributor.author	Karabulut, Solmaz
dc.date.accessioned	2019-12-16T09:18:49Z
dc.date.available	2019-12-16T09:18:49Z
dc.date.issued	2009
dc.identifier.issn	0032-3896
dc.identifier.uri	https://doi.org/10.1295/polymj.PJ2009011
dc.identifier.uri	http://hdl.handle.net/11655/19620
dc.description.abstract	The use of electro-induced Mo and W-based catalysts has been investigated in the ring opening metathesis polymerization (ROMP) of 1,3,5,7-cyclooctatetraene (COT). The soluble and conjugated polyacetylene (PA) was obtained under ambient temperature and pressure without employing any secondary reagent (comonomer, chain transfer agent) or substituted monomer (R-COT). NMR analysis results show that the electrochemical Mo-based system leads to a completely (100%) trans product, however, mainly (80%) trans polymer was obtained with W-based analogue for PA.
dc.language.iso	en
dc.publisher	Soc Polymer Science Japan
dc.relation.isversionof	10.1295/polymj.PJ2009011
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Polymer Science
dc.title	Electro-Induced Early Transition Metal Metathesis Catalyst Systems For The Production Of Polyacetylene
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/publishedVersion
dc.relation.journal	Polymer Journal
dc.contributor.department	Kimya
dc.identifier.volume	41
dc.identifier.issue	8
dc.identifier.startpage	629
dc.identifier.endpage	633
dc.description.index	WoS
dc.description.index	Scopus