dc.contributor.author | Bozkurt, Nihat | |
dc.contributor.author | Tunç, Tuncay | |
dc.contributor.author | Delibaş, Nagihan Çaylak | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.contributor.author | Hökelek, Tuncer | |
dc.date.accessioned | 2019-12-13T06:27:05Z | |
dc.date.available | 2019-12-13T06:27:05Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S160053681301965X | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793697/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18147 | |
dc.description.abstract | In the crystal of the title CdII polymeric complex, [Cd(C7H4ClO2)2(C10H14N2O)(H2O)]n, the CdII cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO6 pentagonal–bipyramidal geometry. The CdII cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Intermolecular O—H⋯O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the molecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxylate groups; the dihedral angles between the carboxylate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°. | |
dc.relation.isversionof | 10.1107/S160053681301965X | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Catena-Poly[[AquaBis(3-ChloroBenzoato-Κ2 O,O′)Cadmium]-Μ-N,N-DiEthylNicoTinAmide-Κ2 N 1:O] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 69 | |
dc.identifier.issue | Pt 8 | |
dc.identifier.startpage | m466 | |
dc.identifier.endpage | m467 | |
dc.description.index | PubMed | |
dc.description.index | Scopus | |