dc.contributor.author | Hökelek,Tuncer | |
dc.contributor.author | Ermis, E. | |
dc.contributor.author | Tercan, B. | |
dc.contributor.author | Çimen ,E. | |
dc.contributor.author | Necefoglu ,H. | |
dc.date.accessioned | 2019-12-13T06:25:37Z | |
dc.date.available | 2019-12-13T06:25:37Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536810022476 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006769/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18131 | |
dc.description.abstract | The crystal structure of the title compound, [Zn2(C8H7O2)4(H2O)2]·[Zn2(C8H7O2)4(C6H6N2O)2]·2H2O, consists of two kinds of dinuclear ZnII complexes (complex A and complex B) and uncoordinated water molecules. In complex A, [Zn2(C8H7O2)4(H2O)2], each Zn cation is chelated by a 4-methylbenzoate (PMB) anion and coordinated by a water molecule, and is further bridged by two PMB anions in a trigonal-bipyramidal geometry. In complex B, [Zn2(C8H7O2)4(C6H6N2O)2], each ZnII cation is coordinated by a monodentate PMB anion and one nicotinamide (NA) ligand, and is further bridged by two PMB anions in a tetrahedral geometry. Weak intra-molecular π–π stacking between adjacent benzene rings is observed in complex B, the centroid–centroid distance being 3.710 (2) Å. Extensive O—H⋯O and N—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding is present in the crystal structure. The crystal studied was a racemic twin; the minor twin component refined to 38%. | |
dc.relation.isversionof | 10.1107/S1600536810022476 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Bis(Μ-4-MethylBenzoato-Κ2 O:O′)Bis[Aqua(4-MethylBenzoato-Κ2 O,O′)Zinc(II)]–Bis(Μ-4-MethylBenzoato-Κ2 O:O′)Bis[(4-MethylBenzoato-Κo)(Nicotinamide-Κn)Zinc(II)]–Water (1/1/2) | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 66 | |
dc.identifier.issue | Pt 7 | |
dc.identifier.startpage | m841 | |
dc.identifier.endpage | m842 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |