Bis(Μ-4-MethylBenzoato)-Κ3 O,O′:O;Κ3 O:O,O′-Bis[Aqua(4-MethylBenzoato-Κ2 O,O′)(Nicotinamide-Κn 1)Cadmium]
Tarih
2012Yazar
Dinçel, Öznur
Tercan, Barış
Çimen, E.
Necefoğlu, Hacali
Hökelek, Tuncer
Üst veri
Tüm öğe kaydını gösterÖzet
In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O)2(H2O)2], the CdII ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the CdII ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.
Bağlantı
https://doi.org/10.1107/S1600536812047046https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588758/
http://hdl.handle.net/11655/18130