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dc.contributor.authorHOKELEK, T
dc.contributor.authorKILIC, Z
dc.contributor.authorKILIC, A
dc.date.accessioned2019-12-13T06:35:46Z
dc.date.available2019-12-13T06:35:46Z
dc.date.issued2009
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536809033200
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969956/
dc.identifier.urihttp://hdl.handle.net/11655/18602
dc.description.abstractThe asymmetric unit of the crystal structure of the title complex, [Co(C6H6N2O)2(H2O)4](C8H5O3)2·2H2O, contains one-half of the complex cation with the CoII ion located on an inversion center, a 4-formyl­benzoate (FB) counter-anion and an uncoordinated water mol­ecule. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement with an average Co—O bond length of 2.086 Å; the slightly distorted octa­hedral coordination is completed by the two N atoms of the isonicotinamide (INA) ligands at a slightly longer distance [2.1603 (14) Å] in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 5.93 (13)°, while the pyridine and benzene rings are oriented at a dihedral angle of 3.09 (6)°. In the crystal structure, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π Contacts between the benzene and pyridine rings [centroid–centroid distance = 3.758 (1) Å] may further stabilize the crystal structure.
dc.relation.isversionof10.1107/S1600536809033200
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleTetra­Aqua­Bis(Isonicotinamide-Κn1)Cobalt(II) Bis­(4-Formyl­Benzoate) Dihydrate
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume65
dc.identifier.issuePt 9
dc.identifier.startpagem1130
dc.identifier.endpagem1131
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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