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dc.contributor.authorBozkurt, Nihal
dc.contributor.authorDilek, Nefise
dc.contributor.authorÇaylak Delibaş, Nagihan
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned2019-12-13T06:29:14Z
dc.date.available2019-12-13T06:29:14Z
dc.date.issued2013
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S160053681301458X
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684906/
dc.identifier.urihttp://hdl.handle.net/11655/18278
dc.description.abstractIn the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the CoII atom is located on an inversion center and is coordinated by two 3-chloro­benzoate (CB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network lying parallel to (101). π–π stacking between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure.
dc.relation.isversionof10.1107/S160053681301458X
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleDi­Aqua­Bis­(3-Chloro­Benzoato-Κo)Bis­(Nicotinamide-Κn 1)Cobalt(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume69
dc.identifier.issuePt 6
dc.identifier.startpagem349
dc.identifier.endpagem350
dc.description.indexPubMed
dc.description.indexScopus


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