dc.contributor.author | Aşkın, Gülçin Şefiye | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.contributor.author | Tonbul, A. M. | |
dc.contributor.author | Dilek, Nefise | |
dc.contributor.author | Hökelek, Tuncer | |
dc.date.accessioned | 2019-12-13T06:29:09Z | |
dc.date.available | 2019-12-13T06:29:09Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.uri | https://doi.org/10.1107/S2056989016005612 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908509/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18259 | |
dc.description.abstract | In the title centrosymmetric MnII complex, the MnII atom is coordinated by two 4-nitrobenzoate (NB) anions, two nicotinamide (NA) ligands and two water molecules; the NB and NA ligands act as monodentate ligands. The resulting MnN2O4 coordination polyhedron is a distorted octahedron., The asymmetric unit of the title compound, [Mn(C7H4NO4)2(C6H6N2O)2(H2O)2], contains one MnII atom, one 4-nitrobenzoate (NB) anion, one nicotinamide (NA) ligand and one water molecule; NA and NB each act as a monodentate ligand. The MnII atom, lying on an inversion centre, is coordinated by four O atoms and two pyridine N atoms in a distorted octahedral geometry. The water molecules are hydrogen bonded to the carboxylate O atoms. The dihedral angle between the carboxylate group and the adjacent benzene ring is 24.4 (3)°, while the benzene and pyridine rings are oriented at a dihedral angle of 86.63 (11)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the molecules, forming a layer parallel to the ab plane. The layers are further linked via weak C—H⋯O hydrogen bonds, a π–π stacking interaction [centroid–centroid distance = 3.868 (2) Å] and a weak C—H⋯π interaction, resulting in a three-dimensional network. | |
dc.relation.isversionof | 10.1107/S2056989016005612 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Crystal Structure Of Trans-DiAquaBis(Nicotinamide-Κn 1)Bis(4-NitroBenzoato-Κo)Manganese(II) | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Crystallographic Communications | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 72 | |
dc.identifier.issue | Pt 5 | |
dc.identifier.startpage | 656 | |
dc.identifier.endpage | 658 | |
dc.description.index | PubMed | |
dc.description.index | Scopus | |