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dc.contributor.authorAşkın, Gülçin Şefiye
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorTonbul, A. M.
dc.contributor.authorDilek, Nefise
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned2019-12-13T06:29:09Z
dc.date.available2019-12-13T06:29:09Z
dc.date.issued2016
dc.identifier.issn2056-9890
dc.identifier.urihttps://doi.org/10.1107/S2056989016005612
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908509/
dc.identifier.urihttp://hdl.handle.net/11655/18259
dc.description.abstractIn the title centrosymmetric MnII complex, the MnII atom is coordinated by two 4-nitro­benzoate (NB) anions, two nicotinamide (NA) ligands and two water mol­ecules; the NB and NA ligands act as monodentate ligands. The resulting MnN2O4 coordination polyhedron is a distorted octa­hedron., The asymmetric unit of the title compound, [Mn(C7H4NO4)2(C6H6N2O)2(H2O)2], contains one MnII atom, one 4-nitro­benzoate (NB) anion, one nicotinamide (NA) ligand and one water mol­ecule; NA and NB each act as a monodentate ligand. The MnII atom, lying on an inversion centre, is coordinated by four O atoms and two pyridine N atoms in a distorted octa­hedral geometry. The water mol­ecules are hydrogen bonded to the carboxyl­ate O atoms. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 24.4 (3)°, while the benzene and pyridine rings are oriented at a dihedral angle of 86.63 (11)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules, forming a layer parallel to the ab plane. The layers are further linked via weak C—H⋯O hydrogen bonds, a π–π stacking inter­action [centroid–centroid distance = 3.868 (2) Å] and a weak C—H⋯π inter­action, resulting in a three-dimensional network.
dc.relation.isversionof10.1107/S2056989016005612
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleCrystal Structure Of Trans-Di­Aqua­Bis­(Nicotinamide-Κn 1)Bis­(4-Nitro­Benzoato-Κo)Manganese(II)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Crystallographic Communications
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume72
dc.identifier.issuePt 5
dc.identifier.startpage656
dc.identifier.endpage658
dc.description.indexPubMed
dc.description.indexScopus


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