• Türkçe
    • English
  • English 
    • Türkçe
    • English
  • Login
View Item 
  •   DSpace Home
  • Mühendislik Fakültesi
  • Fizik Mühendisliği Bölümü
  • Fizik Mühendisliği Bölümü Makale Koleksiyonu
  • View Item
  •   DSpace Home
  • Mühendislik Fakültesi
  • Fizik Mühendisliği Bölümü
  • Fizik Mühendisliği Bölümü Makale Koleksiyonu
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Crystal Structure Of Trans-Di­Aqua­Bis­(4-Cyano­Benzoato-Κo)Bis­(N,N-Di­Ethyl­Nicotinamide-Κn)Cadmium

View/Open
licence.txt (265bytes)
wm5339.pdf (493.1Kb)
Date
2016
Author
Akduran, Nurcan
Sertçelik, Mustafa
Aydoğdu, Ö.
Necefoğlu, Hacali
Hökelek, Tuncer
xmlui.mirage2.itemSummaryView.MetaData
Show full item record
Abstract
The CdII atom in the title complex, [Cd(C10H14N2O)2(C8H4NO2)2(H2O)2], is located on an inversion centre and is coordinated by an N2O4 donor set from pairs of water, 4-cyano­benzoate and N,N-di­ethyl­nicotinamide ligands., The mononuclear title cadmium complex, [Cd(C10H14N2O)2(C8H4NO2)2(H2O)2], is centrosymmetric and contains two water mol­ecules, two 4-cyanobenzoate (CB) ligands and two di­ethyl­nicotinamide (DENA) ligands. All the ligands are coordinated to the CdII atom in a monodentate mode. The four nearest O atoms around the CdII atom form a slightly distorted square-planar arrangement, with the distorted octa­hedral coordination sphere being completed by the two pyridine N atoms of the DENA ligands at distances of 2.3336 (13) Å. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 8.75 (16)°, while the benzene and pyridine rings are oriented at a dihedral angle of 57.83 (5)°. The water mol­ecules exhibit both intra­molecular [to the non-coordinating carboxyl­ate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.670 (2) Å] and inter­molecular [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.781 (2) Å] O—H⋯O hydrogen bonds. The latter lead to the formation of supra­molecular chains propagating along [110].
URI
https://doi.org/10.1107/S2056989016018247
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137619/
http://hdl.handle.net/11655/18256
xmlui.mirage2.itemSummaryView.Collections
  • Fizik Mühendisliği Bölümü Makale Koleksiyonu [723]
Hacettepe Üniversitesi Kütüphaneleri
Açık Erişim Birimi
Beytepe Kütüphanesi | Tel: (90 - 312) 297 6585-117 || Sağlık Bilimleri Kütüphanesi | Tel: (90 - 312) 305 1067
Bizi Takip Edebilirsiniz: Facebook | Twitter | Youtube | Instagram
Web sayfası:www.library.hacettepe.edu.tr | E-posta:openaccess@hacettepe.edu.tr
Sayfanın çıktısını almak için lütfen tıklayınız.
Contact Us | Send Feedback



DSpace software copyright © 2002-2016  DuraSpace
Theme by 
Atmire NV
 

 


DSpace@Hacettepe
huk openaire onayı
by OpenAIRE

About HUAES
Open Access PolicyGuidesSubcriptionsContact

livechat

sherpa/romeo

Browse

All of DSpaceCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsTypeDepartmentPublisherLanguageRightsxmlui.ArtifactBrowser.Navigation.browse_indexFundingxmlui.ArtifactBrowser.Navigation.browse_subtypeThis CollectionBy Issue DateAuthorsTitlesSubjectsTypeDepartmentPublisherLanguageRightsxmlui.ArtifactBrowser.Navigation.browse_indexFundingxmlui.ArtifactBrowser.Navigation.browse_subtype

My Account

LoginRegister

Statistics

View Usage Statistics

DSpace software copyright © 2002-2016  DuraSpace
Theme by 
Atmire NV