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dc.contributor.authorHökelek,Tuncer
dc.contributor.authorÖzbek, Elif
dc.contributor.authorSertçelik, Mustafa
dc.contributor.authorYenice, Çiğdem Şahin
dc.contributor.authorNecefoğlu, Hacali
dc.date.accessioned2019-12-13T06:27:19Z
dc.date.available2019-12-13T06:27:19Z
dc.date.issued2017
dc.identifier.issn2056-9890
dc.identifier.urihttps://doi.org/10.1107/S2056989017016899
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730262/
dc.identifier.urihttp://hdl.handle.net/11655/18176
dc.description.abstractThe asymmetric unit of the title complex contains one half of the complex mol­ecule, one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbo­nitrile (CPy) mol­ecule; the Bnz anions act as bidentate ligands through the carboxyl­ate O atoms, while the Cpy anion acts as a monodentate N(pyridine)-bonding ligand. The complete centrosymmetric trinuclear complex thus comprises a linear array of three ZnII cations. In the crystal, the Bnz anions link to the Cpy N atoms via weak C—H⋯N hydrogen bonds, forming a two-dimensional network. The Hirshfeld surface analysis confirms the role of H-atom contacts in establishing the packing., The asymmetric unit of the title complex, [Zn3(C7H5O2)6(C6H4N2)2], contains one half of the complex mol­ecule, i.e. one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbo­nitrile (Cpy) mol­ecule; the Bnz anions act as bidentate ligands through the carboxyl­ate O atoms, while the Cpy ligand acts as a monodentate N(pyridine)-bonding ligand. The complete centrosymmetric trinuclear complex thus comprises a linear array of three ZnII cations. The central ZnII cation shows an octa­hedral coordination and is bridged to each of the terminal ZnII cations by three Bnz anions. By additional coordination of the CPy ligand, the terminal ZnII cations adopt a trigonal–pyramidal coordination environment. In the crystal, the Bnz anions link to the Cpy N atoms via weak C—H⋯N hydrogen bonds, forming a two-dimensional network. C—H⋯π and π–π inter­actions [between the benzene and pyridine rings of adjacent mol­ecules with an inter­centroid distance of 3.850 (4) Å] help to consolidate a three-dimensional architecture. The Hirshfeld surface analysis confirms the role of H-atom contacts in establishing the packing.
dc.relation.isversionof10.1107/S2056989017016899
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleCrystal Structure And Hirshfeld Surface Analysis Of Hexa­Kis­(Μ-Benzoato-Κ2 O:O′)Bis­(Pyridine-3-Carbo­Nitrile-Κn 1)Trizinc(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Crystallographic Communications
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume73
dc.identifier.issuePt 12
dc.identifier.startpage1966
dc.identifier.endpage1970
dc.description.indexPubMed
dc.description.indexScopus


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