Basit öğe kaydını göster

dc.contributor.authorÇelik, Fatih
dc.contributor.authorDilek, Nefise
dc.contributor.authorÇaylak Delibas, Nagihan
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned2019-12-13T06:27:07Z
dc.date.available2019-12-13T06:27:07Z
dc.date.issued2013
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536813032297
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/
dc.identifier.urihttp://hdl.handle.net/11655/18150
dc.description.abstractIn the title polymeric compound, [Cu(C8H5O3)2(C4H4N2)(H2O)2]n, the CuII atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monodentate formyl­benzoate anions and by two N atoms of the bridging pyrazine ligand, which is bis­ected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water mol­ecules. In the formyl­benzoate anion, the carboxyl­ate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the CuII cations, forming polymeric chains running along the b-axis direction. Strong intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate O atoms. In the crystal, O—Hwater⋯Owater hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—Hpyrazine⋯Oform­yl hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π inter­actions present.
dc.relation.isversionof10.1107/S1600536813032297
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleCatena-Poly[[Di­Aqua­Bis­(4-Formyl­Benzoato-Κo 1)Copper(Ii)]-Μ-Pyrazine-Κ2 N:N′]
dc.typeinfo:eu-repo/semantics/article
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume70
dc.identifier.issuePt 1
dc.identifier.startpagem4
dc.identifier.endpagem5
dc.description.indexPubMed
dc.description.indexScopus


Bu öğenin dosyaları:

Bu öğe aşağıdaki koleksiyon(lar)da görünmektedir.

Basit öğe kaydını göster