dc.contributor.author | Hökelek,T. | |
dc.contributor.author | Yılmaz, F. | |
dc.contributor.author | Tercan, B. | |
dc.contributor.author | Özbek, F. E. | |
dc.contributor.author | Necefoglu , H. | |
dc.date.accessioned | 2019-12-13T06:25:36Z | |
dc.date.available | 2019-12-13T06:25:36Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536809048089 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971791/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18127 | |
dc.description.abstract | The asymmetric unit of the title compound, [Zn2(C7H4FO2)4(C6H6N2O)2]·C7H5FO2, consists of a binuclear ZnII complex bridged by two carboxyl groups of 2-fluorobenzoate (FB) anions and a 2-fluorobenzoic acid molecule. The two bridging FB anions, one chelating FB anion and one nicotinamide (NA) ligand coordinate to one Zn cation with a distorted square-pyramidal geometry, while the two bridging FB anions, one monodentate FB anion and one NA ligand coordinate to the other Zn cation with a distorted tetrahedral geometry. Within the binuclear molecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14)°. In the crystal structure, the uncoordinated 2-fluorobenzoic acid molecules are linked by O—H⋯O hydrogen bonding, forming centrosymmetric supramolecular dimers. Intermolecular N—H⋯O hydrogen bonds link the complex molecules into a three-dimensional network. The π–π contacts between nearly parallel pyridine and benzene rings [dihedral angles of 19.41 (14) and 12.72 (16)°, respectively, centroid–centroid distances = 3.701 (2) and 3.857 (3) Å] may further stabilize the crystal structure. The fluorine atoms in two FB ligands are disordered over two positions, with occupancy ratios of 0.70:0.30. | |
dc.relation.isversionof | 10.1107/S1600536809048089 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Bis(Μ-2-FluoroBenzoato-1:2Κ2 O:O′)(2-FluoroBenzoato-1Κ2 O,O′)(2-FluoroBenzoato-2Κo)Dinicotinamide-1Κn 1,2Κn 1-Dizinc(II)–2-FluoroBenzoic Acid (1/1) | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 65 | |
dc.identifier.issue | Pt 12 | |
dc.identifier.startpage | m1608 | |
dc.identifier.endpage | m1609 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |