Aquabis(3-ChloroBenzoato-kO)Bis(N,N-DiEthylNicotinamide-kN)Copper(II)
Date
2013Author
Bozkurt, Nihat
Tunç, Tuncay
Delibaş, N. Çaylak
Necefoğlu, Hacali
Hökelek, Tuncer
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The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O—H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction.
URI
https://doi.org/10.1107/S1600536813018989https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793693/
http://hdl.handle.net/11655/18112