dc.contributor.author | Karabulut, Solmaz | |
dc.date.accessioned | 2019-12-16T09:18:49Z | |
dc.date.available | 2019-12-16T09:18:49Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0032-3896 | |
dc.identifier.uri | https://doi.org/10.1295/polymj.PJ2009011 | |
dc.identifier.uri | http://hdl.handle.net/11655/19620 | |
dc.description.abstract | The use of electro-induced Mo and W-based catalysts has been investigated in the ring opening metathesis polymerization (ROMP) of 1,3,5,7-cyclooctatetraene (COT). The soluble and conjugated polyacetylene (PA) was obtained under ambient temperature and pressure without employing any secondary reagent (comonomer, chain transfer agent) or substituted monomer (R-COT). NMR analysis results show that the electrochemical Mo-based system leads to a completely (100%) trans product, however, mainly (80%) trans polymer was obtained with W-based analogue for PA. | |
dc.language.iso | en | |
dc.publisher | Soc Polymer Science Japan | |
dc.relation.isversionof | 10.1295/polymj.PJ2009011 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.subject | Polymer Science | |
dc.title | Electro-Induced Early Transition Metal Metathesis Catalyst Systems For The Production Of Polyacetylene | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Polymer Journal | |
dc.contributor.department | Kimya | |
dc.identifier.volume | 41 | |
dc.identifier.issue | 8 | |
dc.identifier.startpage | 629 | |
dc.identifier.endpage | 633 | |
dc.description.index | WoS | |
dc.description.index | Scopus | |