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dc.contributor.authorKarabulut, Solmaz
dc.date.accessioned2019-12-16T09:18:49Z
dc.date.available2019-12-16T09:18:49Z
dc.date.issued2009
dc.identifier.issn0032-3896
dc.identifier.urihttps://doi.org/10.1295/polymj.PJ2009011
dc.identifier.urihttp://hdl.handle.net/11655/19620
dc.description.abstractThe use of electro-induced Mo and W-based catalysts has been investigated in the ring opening metathesis polymerization (ROMP) of 1,3,5,7-cyclooctatetraene (COT). The soluble and conjugated polyacetylene (PA) was obtained under ambient temperature and pressure without employing any secondary reagent (comonomer, chain transfer agent) or substituted monomer (R-COT). NMR analysis results show that the electrochemical Mo-based system leads to a completely (100%) trans product, however, mainly (80%) trans polymer was obtained with W-based analogue for PA.
dc.language.isoen
dc.publisherSoc Polymer Science Japan
dc.relation.isversionof10.1295/polymj.PJ2009011
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectPolymer Science
dc.titleElectro-Induced Early Transition Metal Metathesis Catalyst Systems For The Production Of Polyacetylene
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalPolymer Journal
dc.contributor.departmentKimya
dc.identifier.volume41
dc.identifier.issue8
dc.identifier.startpage629
dc.identifier.endpage633
dc.description.indexWoS
dc.description.indexScopus


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