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An Efficient Water-Mediated Synthetic Route For The Alkylation of Heteroarenes

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Date
2018
Author
Seyitdanlıoglu, Pınar
Hanashalshahaby, Essam Hamied Ahmed
Unaleroglu, Canan
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Abstract
An efficient synthetic route has been described for the alkylation of 1H-indole, 1H-benzimidazole, and 1H-benzotriazole. This approach features the alkylation of heteroaromatics through in situ generated enones from ketonic Mannich bases under metal-free conditions. A series of alkylated heteroaromatics have been synthesized via the K10 catalyzed alkylation reactions of these heteroaromatics with a variety of ketonic Mannich bases. Environmentally benign K10 catalyst, water-mediated mild reaction conditions, and the efficient synthesis of alkylated products are the advantages of this alkylation method.
URI
https://doi.org/10.3906/kim-1802-18
http://hdl.handle.net/11655/19668
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