dc.contributor.author | Hökelek, Tuncer | |
dc.contributor.author | Necefoğlu , Hacali | |
dc.date.accessioned | 2019-12-13T06:36:00Z | |
dc.date.available | 2019-12-13T06:36:00Z | |
dc.date.issued | 1999 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | https://doi.org/10.1107/S0108270199006733 | |
dc.identifier.uri | http://hdl.handle.net/11655/18624 | |
dc.description.abstract | The title compound, [Co(C7H5O3)(2)(C6H6N2O)(2)(H2O)(2)]. is a monomeric and centrosymmetric cobalt complex. It contains two 3-hydroxybenzoate anions, two nicotinamide (NA) molecules and two water molecules as ligands. Each ligand is monodentate, The two nearest carboxylate O atoms and the two water O atoms form a slightly distorted square-planar arrangement around the Co atom [with distances of 2.099 (3) and 2.132 (3) Angstrom, respectively], while the distorted octahedral coordination is completed by the pyridine N atoms of the NA ligands at a distance of 2.139 (4) Angstrom. There is an intramolecular hydrogen bond between the nicotinamide N and O atoms [N ... O 2.228(6) Angstrom], and the hydroxybenzoate and water O atoms form inter- [2.662(5) Angstrom] and intramolecular [2.586 (5) Angstrom] hydrogen bonds, respectively, with the non-coordinated O atom of the carboxylate group. | |
dc.language.iso | en | |
dc.publisher | Munksgaard Int Publ Ltd | |
dc.relation.isversionof | 10.1107/S0108270199006733 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.subject | Chemistry | |
dc.subject | Crystallography | |
dc.title | Trans-Diaquabis(3-Hydroxybenzoato-O)Bis-(Nicotinamide-N-1)Cobalt(Ii) | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section C-Crystal Structure Communications | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 55 | |
dc.identifier.startpage | 1438 | |
dc.identifier.endpage | 1440 | |
dc.description.index | WoS | |
dc.description.index | Scopus | |