dc.contributor.author | Hökelek, Tuncer | |
dc.contributor.author | Yılmaz, Filiz | |
dc.contributor.author | Tercan, Barış | |
dc.contributor.author | Aybirdi, Özgür | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.date.accessioned | 2019-12-13T06:35:53Z | |
dc.date.available | 2019-12-13T06:35:53Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536809040409 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971338/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18615 | |
dc.description.abstract | The title molecule, [Zn2(C8H8NO2)4(C10H14N2O)2]·2H2O, is a centrosymmetric binuclear complex, with two ZnII ions [Zn⋯Zn’ = 2.9301 (4) Å] bridged by four methylaminobenzoate (MAB) ligands. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement with the distorted square-pyramidal coordination completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) ligand. Each ZnII ion is displaced by 0.3519 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.030 Å. The dihedral angles between carboxylate groups and adjacent benzene rings are 10.57 (10) and 16.63 (12)°, while the benzene rings are oriented at a dihedral angle of 81.84 (5)°. The pyridine ring is oriented at dihedral angles of 40.49 (6) and 51.25 (6)° with respect to the benzene rings. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The π–π contact between the inversion-related pyridine rings [centroid–centroid distance = 3.633 (1) Å] may further stabilize the crystal structure. | |
dc.relation.isversionof | 10.1107/S1600536809040409 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | TetraKis[Μ-4-(MethylAmino)Benzoato-Κ2 O:O′]Bis[(N,N-DiethylNicotinamide-N 1)Zinc(II)] Dihydrate | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 65 | |
dc.identifier.issue | Pt 11 | |
dc.identifier.startpage | m1328 | |
dc.identifier.endpage | m1329 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |