dc.contributor.author | Hökelek, Tuncer | |
dc.contributor.author | Dal, Hakan | |
dc.contributor.author | Tercan, Barış | |
dc.contributor.author | Aybirdi, Özgür | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.date.accessioned | 2019-12-13T06:35:53Z | |
dc.date.available | 2019-12-13T06:35:53Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536809047473 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971944/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18614 | |
dc.description.abstract | The title molecule, [Zn2(C9H10NO2)4(C10H14N2O)2], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxylate groups from the dimethylaminobenzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.0416 (12) Å. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intramolecular C—H⋯O and intermolecular C—H⋯π interactions are present. | |
dc.relation.isversionof | 10.1107/S1600536809047473 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | TetraKis[Μ-4-(DimethylAmino)Benzoato-Κ2 O:O′]Bis[(N,N-DiethylNicotinamide-Κn 1)Zinc(II)] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 65 | |
dc.identifier.issue | Pt 12 | |
dc.identifier.startpage | m1582 | |
dc.identifier.endpage | m1583 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |