dc.contributor.author | Hökelek, Tuncer | |
dc.contributor.author | Yılmaz, Filiz | |
dc.contributor.author | Tercan, Barış | |
dc.contributor.author | Aybirdi, Özgür | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.date.accessioned | 2019-12-13T06:35:52Z | |
dc.date.available | 2019-12-13T06:35:52Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536809027986 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977087/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18613 | |
dc.description.abstract | In the centrosymmetric binuclear title complex, [Zn2(C11H14NO2)4(C10H14N2O)2], the two ZnII ions [Zn⋯Zn = 2.8874 (3) Å] are bridged by four 4-(diethylamino)benzoate (DEAB) ligands. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand at a distance of 2.0484 (12) Å. The dihedral angle between the benzene ring and the carboxylate group is 4.89 (6)° in one of the independent DEAB ligands and 7.13 (7)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.58 (5)°. The pyridine ring is oriented at dihedral angles of 31.17 (4) and 58.38 (4)° with respect to the two benzene rings. In the crystal, weak intermolecular C—H⋯O interactions link the molecules into a three-dimensional network. Two weak C—H⋯π interactions are also present. The two ethyl groups of one of the DEAB ligands are disordered over two orientations, with occupancy ratios of 0.798 (5):0.202 (5) and 0.890 (5):0.110 (5). | |
dc.relation.isversionof | 10.1107/S1600536809027986 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | TetraKis[Μ-4-(DiethylAmino)Benzoato-Κ2 O:O′]Bis[(N,N-DiethylNicotinamide-Κn 1)Zinc(II)] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 65 | |
dc.identifier.issue | Pt 8 | |
dc.identifier.startpage | m955 | |
dc.identifier.endpage | m956 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |