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dc.contributor.authorHökelek, Tuncer
dc.contributor.authorYılmaz, Filiz
dc.contributor.authorTercan, Barış
dc.contributor.authorAybirdi, Özgür
dc.contributor.authorNecefoğlu, Hacali
dc.date.accessioned2019-12-13T06:35:52Z
dc.date.available2019-12-13T06:35:52Z
dc.date.issued2009
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536809027986
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977087/
dc.identifier.urihttp://hdl.handle.net/11655/18613
dc.description.abstractIn the centrosymmetric binuclear title complex, [Zn2(C11H14NO2)4(C10H14N2O)2], the two ZnII ions [Zn⋯Zn = 2.8874 (3) Å] are bridged by four 4-(diethyl­amino)benzoate (DEAB) ligands. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the pyridine N atom of an N,N-diethyl­nicotinamide (DENA) ligand at a distance of 2.0484 (12) Å. The dihedral angle between the benzene ring and the carboxyl­ate group is 4.89 (6)° in one of the independent DEAB ligands and 7.13 (7)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.58 (5)°. The pyridine ring is oriented at dihedral angles of 31.17 (4) and 58.38 (4)° with respect to the two benzene rings. In the crystal, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present. The two ethyl groups of one of the DEAB ligands are disordered over two orientations, with occupancy ratios of 0.798 (5):0.202 (5) and 0.890 (5):0.110 (5).
dc.relation.isversionof10.1107/S1600536809027986
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleTetra­Kis[Μ-4-(Diethyl­Amino)Benzoato-Κ2 O:O′]Bis­[(N,N-Diethyl­Nicotinamide-Κn 1)Zinc(II)]
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume65
dc.identifier.issuePt 8
dc.identifier.startpagem955
dc.identifier.endpagem956
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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