dc.contributor.author | Aydın, Ömür | |
dc.contributor.author | Çaylak Delibaş, Nagihan | |
dc.contributor.author | Necefoğlu, Hacali | |
dc.contributor.author | Hökelek, Tuncer | |
dc.date.accessioned | 2019-12-13T06:35:49Z | |
dc.date.available | 2019-12-13T06:35:49Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536812010367 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343818/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18608 | |
dc.description.abstract | In the centrosymmetric binuclear title complex, [Cu2(C7H4IO2)4(H2O)2], the two CuII ions [Cu⋯Cu = 2.6009 (5) Å] are bridged by four 2-iodobenzoate (IB) ligands. The four nearest O atoms around each CuII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the O atom of the water molecule at a distance of 2.1525 (16) Å. The dihedral angle between the benzene ring and the carboxylate group is 25.67 (13)° in one of the independent IB ligands and 6.44 (11)° in the other. The benzene rings of the two independent IB ligands are oriented at a dihedral angle of 86.61 (7)°. In the crystal, O—H⋯O interactions link the molecules into a two-dimensional network. π–π contacts between the benzene rings [centroid–centroid distances = 3.810 (2) and 3.838 (2) Å] may further stabilize the structure. | |
dc.relation.isversionof | 10.1107/S1600536812010367 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | TetraKis(Μ-2-IodoBenzoato-Κ2 O:O′)Bis[AquaCopper(II)] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 68 | |
dc.identifier.issue | Pt 4 | |
dc.identifier.startpage | m409 | |
dc.identifier.endpage | m410 | |
dc.description.index | PubMed | |
dc.description.index | Scopus | |