dc.contributor.author | Necefoğlu, Hacali | |
dc.contributor.author | Özbek, Füreya Elif | |
dc.contributor.author | Öztürk, Vijdan | |
dc.contributor.author | Tercan, Barış | |
dc.contributor.author | Höleke, Tuncer | |
dc.date.accessioned | 2019-12-13T06:34:27Z | |
dc.date.available | 2019-12-13T06:34:27Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 1600-5368 | |
dc.identifier.uri | https://doi.org/10.1107/S1600536811021921 | |
dc.identifier.uri | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151798/ | |
dc.identifier.uri | http://hdl.handle.net/11655/18446 | |
dc.description.abstract | In the crystal structure of the title complex, [Mn(C7H4FO2)2(H2O)2]n, the MnII atom is located on an inversion centre. It is coordinated by two water molecules in the apical directions and four 4-fluorobenzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the MnII atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two O atoms of the water molecules. The dihedral angle between the carboxylate group and the adjacent benzene ring is 27.29 (16)°. The O—H⋯O hydrogen bonds further connect the manganese-carboxylate units. π–π contacts between the benzene rings [centroid-centroid distance = 3.6894 (15) Å] further stabilize the crystal structure. | |
dc.relation.isversionof | 10.1107/S1600536811021921 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.title | Poly[[DiaquaManganese(Ii)]-Bis(Μ-4-FluoroBenzoato-Κ2 O:O′)] | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.relation.journal | Acta Crystallographica Section E: Structure Reports Online | |
dc.contributor.department | Fizik Mühendisliği | |
dc.identifier.volume | 67 | |
dc.identifier.issue | Pt 7 | |
dc.identifier.startpage | m1003 | |
dc.identifier.endpage | m1004 | |
dc.description.index | PubMed | |
dc.description.index | WoS | |
dc.description.index | Scopus | |