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dc.contributor.authorAybirdi, Özgür
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorTercan, Barış
dc.contributor.authorDal, Hakan
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned2019-12-13T06:29:26Z
dc.date.available2019-12-13T06:29:26Z
dc.date.issued2009
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536809016602
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969611/
dc.identifier.urihttp://hdl.handle.net/11655/18307
dc.description.abstractThe title CoII complex, [Co(C9H10NO2)2(C6H6N2O)(H2O)2], contains two 4-dimethyl­amino­benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water mol­ecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Co atom form a highly distorted square-planar arrangement, while the distorted octa­hedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water mol­ecule in the axial positions. An intra­molecular O—H⋯O hydrogen bond between the monodentate-coordinated carboxyl group and a coordinated water mol­ecule results in a six-membered ring with an envelope conformation. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 4.29 (10)° for the monodentate ligand and 2.31 (13)° for the bidentate ligand, while the two benzene rings are oriented at a dihedral angle of 65.02 (5)°. The dihedral angles between the pyridine and benzene rings are 11.21 (5)° for the monodentate ligand and 74.60 (5)° for the bidentate ligand. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure.
dc.relation.isversionof10.1107/S1600536809016602
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleDiaqua­Bis[4-(Dimethyl­Amino)­Benzoato]-Κ2 O,O′;Κo-(Isonicotinamide-Κn1)Cobalt(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume65
dc.identifier.issuePt 6
dc.identifier.startpagem627
dc.identifier.endpagem628
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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