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dc.contributor.authorHökelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Barış
dc.contributor.authorAybirdi, Özgür
dc.contributor.authorNecefoğlu, Hacali
dc.date.accessioned2019-12-13T06:29:24Z
dc.date.available2019-12-13T06:29:24Z
dc.date.issued2009
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536809030980
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970090/
dc.identifier.urihttp://hdl.handle.net/11655/18303
dc.description.abstractThe title CoII complex, [Co(C9H10NO2)2(C10H14N2O)2(H2O)2], is centrosymmetric. It contains two dimethyl­amino­benzoate (DMAB) and two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxyl­ate group by −0.781 (1) Å. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present.
dc.relation.isversionof10.1107/S1600536809030980
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleDiaqua­Bis­(N,N-Diethyl­Nicotinamide-Κn1)Bis[4-(Dimethyl­Amino)­Benzoato-Κo]Cobalt(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume65
dc.identifier.issuePt 9
dc.identifier.startpagem1051
dc.identifier.endpagem1052
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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