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dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorÇimen, Efdal
dc.contributor.authorTercan, Barış
dc.contributor.authorErmiş, Emel
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned2019-12-13T06:29:23Z
dc.date.available2019-12-13T06:29:23Z
dc.date.issued2010
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536810013954
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979235/
dc.identifier.urihttp://hdl.handle.net/11655/18302
dc.description.abstractIn the centrosymmetric mononuclear title complex, [Co(C8H7O2)2(C10H14N2O)2(H2O)2], the CoII ion is located on an inversion center. The asymmetric unit contains one 4-methyl­benzoate (PMB) anion, one N,N-diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 3.73 (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.28 (6)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (001). The structure is further stabilized by π–π contacts between the pyridine rings [centroid–centroid distance = 3.544 (1) Å] and weak C—H⋯π inter­actions involving the benzene ring.
dc.relation.isversionof10.1107/S1600536810013954
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleDiaqua­Bis(N,N-Diethyl­Nicotinamide-Κn 1)Bis­(4-Methyl­Benzoato-Κo)Cobalt(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume66
dc.identifier.issuePt 5
dc.identifier.startpagem556
dc.identifier.endpagem557
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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