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dc.contributor.authorHökelek, Tuncer
dc.contributor.authorDal, Hakan
dc.contributor.authorTercan, Barış
dc.contributor.authorÖzbek, F. Elif
dc.contributor.authorNecefoğlu, Hacali
dc.date.accessioned2019-12-13T06:29:13Z
dc.date.available2019-12-13T06:29:13Z
dc.date.issued2009
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536809011209
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968958/
dc.identifier.urihttp://hdl.handle.net/11655/18273
dc.description.abstractThe title NiII complex, [Ni(C7H4ClO2)2(C6H6N2O)2(H2O)2], is centrosymmetric with the Ni atom located on an inversion centre. The mol­ecule contains two 2-chloro­benzoate (CB) and two nicotinamide (NA) ligands and two water mol­ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.48 (16)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.16 (5)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into infinite chains. π–π Contacts between the benzene and pyridine rings [centroid–centroid distance = 3.952 (1) Å] may further stabilize the crystal structure. There is also a C—H⋯π inter­action.
dc.relation.isversionof10.1107/S1600536809011209
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleDiaqua­Bis(2-Chloro­Benzoato-Κo)Bis­(Nicotinamide-Κn1)Nickel(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume65
dc.identifier.issuePt 4
dc.identifier.startpagem466
dc.identifier.endpagem467
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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