Catena-Poly[AquaBis(Μ-3-ChloroBenzoAto-Κ2 O:O′)Zinc]
Tarih
2013Yazar
Bozkurt, Nihat
Dilek, Nefise
Delibaş, Nagihan Çaylak
Necefoğlu, Hacali
Hökelek, Tuncer
Üst veri
Tüm öğe kaydını gösterÖzet
In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chlorobenzoate anions and by one water molecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxylate group is twisted away from the attached benzene ring by 44.16 (11)°. The chlorobenzoate anion bridges ZnII cations, forming polymeric chains running along the c-axis direction. O—H⋯O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane.
Bağlantı
https://doi.org/10.1107/S160053681301564Xhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772418/
http://hdl.handle.net/11655/18152